Copper-catalyzed coupling reaction of unactivated secondary alkyl iodides with alkyl Grignard reagents in the presence of 1,3-butadiene as an effective additive.
نویسندگان
چکیده
Cu-catalyzed cross-coupling of unactivated secondary alkyl iodides with alkyl Grignard reagents in the presence of 1,3-butadiene as a ligand precursor was developed. The use of 1,3-butadiene resulted in improved yields of alkyl-alkyl products with improved selectivities.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 74 شماره
صفحات -
تاریخ انتشار 2012